硼的地球化学性质及其在俯冲带的循环与成矿初探

硼是广泛应用于化工、农业、材料科学及核工业领域的重要元素。硼与氢的核聚变反应是未来具备运用潜力的清洁能源。硼作为典型的亲石元素,是高度不相容元素。硼元素容易富集于蚀变洋壳及蛇纹石化地幔橄榄岩中。而在板块俯冲过程中,由于硼具有强的流体活动性,会优先赋存于流体中。因此,当蛇纹石化的大洋岩石圈及覆于其上的沉积物在俯冲过程中发生脱水,这使得弧前地幔楔发生大规模的蛇纹石化。此时大量硼元素很可能随俯冲流体释放并封存于弧前地幔楔中。目前已发现的超大型硼矿床主要位于聚合型板块边缘,尤其土耳其拥有世界上最大的硼酸盐储量。我们推测这些矿床的形成基础条件之一可能与弧前高度蛇纹石化的地幔楔有关。尤其是在洋 陆俯冲环境,弧前蛇纹岩或蛇绿混杂岩首先通过俯冲侵蚀再循环到火山弧岩浆中,使得岩浆更富集硼。随后弧火山喷发大量富硼的火山岩、岩浆热液及水气。在岩浆冷却过程中,硼元素析出、沉淀于火山表面,并伴随风化、侵蚀过程汇聚至碰撞造山带的封闭湖盆之中。此外,干冷的气候条件下也进一步促进了硼的成矿。我国具有形成大型、超大型硼矿的地质条件,应加大研究及探勘力度,并适当购买硼作为战略储备。     

自然重砂成因矿物学特征及找矿指示作用

自然重砂是地质体经自然风化、剥蚀、搬运、沉积等地质作用而分离出的单矿物(或矿物组合)。自然重砂矿物晶体由于仍然保留有许多矿物成因信息,包括颜色、形态、化学成分、物理性质和矿物组合等特征,因此常用于追溯源区地质体或者找矿勘查。这种方法被认为是一种经济实用的找矿方法——自然重砂测量。本文基于全国自然重砂找矿的数据资料,系统梳理了自然重砂的矿物类型、出现频率及其分布等特点,分析了自然重砂的矿物组合和成因矿物学特征,研究了自然重砂矿物的源区烙印、搬运距离及标型指示矿物组合特征,探讨了自然重砂成因矿物学研究意义及其找矿应用前景。自然重砂矿物的颜色、形态及内部结构依然保留着明确的成因矿物学信息:其颜色和晶体形态具有继承性而与其源区母体联系起来,体现源区母体的特性;其矿物组成可分出残余原生重矿物(包括造岩矿物、副矿物、矿石矿物等)和新生重砂矿物两个部分,如赤铜矿、孔雀石等反映着源区岩性体的成分或者赋存状态特征,其矿物组合也在很大程度上继承原生共生矿物而体现诸如有无矿化等意义;重砂颗粒的磨圆度、边界光滑性等表面特征反映搬运距离,有利于明确响应源区母体或者物源,而具有良好的找矿指示意义。     

Relict mountain slope deposits of northern Portugal: facies,sedimentogenesis and environmental implications

This paper deals with the formation processes and the palaeoenvironmental significance of relict slope deposits located on the uppermost part of the north Portugal mountains. For this purpose, seven key sites representative of the different lithofacies have been selected and analysed in detail. The data show that three main dynamic processes are responsible for the emplacement of regional fossil slope deposits: runoff, debris flows and dry grain flows. The ubiquity of these processes and the lack of frost‐related features or landforms do not support the existence of severe Pleistocene climates in this part of the lberian Peninsula as postulated by previous work. Pedological data gathered at one of the study sites show that a subalpine environment was probably present at 700–800 m altitude between 29 and 14 kyr. Using data from the Pyrenees Mountains, a 6.5 to 12°C depression in mean annual temperature has been tentatively postulated for this Pleniglacial period. Copyright © 2003 John Wiley & Sons, Ltd.     

The grain-size characteristics of Quaternary deposits at Xingshan near Siping in Jilin province, China

This research paper analyses the grain-size characteristics of the Quaternary deposits at Xingshan near Siping, Jilin province in China by employing graphic measures to study the grain size distribution and its mode of transport and deposition. The Quaternary deposits at Xingshan lie unconformable on Cretaceous rocks made of siltstone, mudstone and sandstone. The average grain size is between 8.06 to 8.55Φ (0.002 6 ～0.003 7 mm). The Quaternary deposits at Xingshan mainly compose of very fine silt to clay. The compositions of the grade are clay 63% and silt 37%. The clay size components are weathered debris transported and deposited by flowing water from the SE highlands or hills to the low lying NW Xingshan plains whereas the silty components accumulated by aoelian process. The Quaternary deposits at Xingshan accumulated in the middle and late Pleistocene interglacial periods from (459.12～39.03) ka to (88.92～7.56) ka. The standard deviation ranged from 0.96 to 1.36Φ, indicating that the sediments are moderately to poorly sorted, Coefficient of skewness ranged from 0.16～0.31 with an average skewness of 0.218, (Positively skewed towards fine). Kurtosis values (0.84～1.05) from the grain size distribution and visual inspection of the frequency curves indicate platykurtic to mesokurtic curves and unimodal to bimodal grain-size distribution. The type of deposit formation is sand dune and the source is at a distal from its provenance.     

上扬子地台震旦系铅锌矿床类型及找矿方向

上扬子地台含铅锌矿地层主要为震旦系。震旦系在上扬子地台主要发育上统灯影组,次有下统陡山沱组。将上扬子地台震旦系铅锌矿床成因划分为一级为叠生矿床,二级为层控矿床,三级为热水沉积改造矿床和热水沉积再造矿床四级类型,该类型按铅锌比例进一步划分为富铅型、富锌型、铅锌共生型。研究区内最重要的铅锌矿床成因类型为南郑马元、会东大梁子铅锌矿为代表的富锌型。陕西南郑、紫阳—镇坪地区,湖北武当、神农架、黄陵地区,以及地台西缘的安宁河、甘洛—小江、峨边—寻甸等地区的震旦系是寻找铅锌矿的最有利地段。     

四川石棉独立碲矿床蚀变岩的地质地球化学研究

四川石棉大水沟独立碲矿床堪称世界首例，其矿体两侧的围岩蚀变较窄，且蚀变带与矿脉及未蚀变岩呈清楚而截然的接触关系。主要围岩蚀变为白云石化、白（绢）云母化、云英岩化及电气石化等。这些蚀变作用分别发生于１７７．７～１６５．１Ｍａ和９１．７１～８０．１９Ｍａ。蚀变作用过程中ＳｉＯ２大量析出，Ａｌ２Ｏ３、ＴｉＯ２、ＣａＯ、ＭｇＯ、Ｋ２Ｏ、Ｈ２Ｏ、ＣＯ２、Ｆｅ２Ｏ３、ＭｎＯ则有不同程度地带入。与此同时，ＲＥＥ在此过程中包集体迁出，Ｔｅ、Ｂｉ、ＡＳ等元素的含量则决定于蚀变作用及其强度，而与原岩无关。     

山东内生金矿矿床谱系及其致矿地质异常

矿床谱系是对成矿多样性的理论概括,而成矿多样性又是由不同级别、不同性质的致矿地质异常决定的.本文论述了山东省内生金矿矿床谱系及其致矿地质异常.     

凤太矿田层控铅锌(铜)矿床的成矿物质来源探讨

秦岭凤太矿田层控铅锌(铜)矿床的金属物质、硫和成矿溶液主要来自深部基底的岩石,属海底喷流—沉积成因矿床。从这一理论认识出发可进一步分析控矿地质条件及今后在该区有效地寻找同类矿床。     

Optimization of grid-drilling using computer simulation

A computer simulation method has been developed to find efficient drilling grids for mineral deposits. A well-known ore deposit is used as a model to develop an efficient pattern for undiscovered ore bodies in the same area or in other prospects where similar geometry is suspected. The model for this study is the Austinville, Virginia deposit, a Mississippi Valley-type deposit composed of 17 ore bodies totaling 34 million short tons (30 million metric tons). The method employs a computer program that simulates drilling the model deposit with different patterns, including various levels of follow-up drilling. Follow-up holes are drilled in fences at one half the original spacing around holes in the grid that show ore-grade mineralization. Each pattern is drilled 100 times from random starting locations to provide a range of outcomes of drilling, including the best, worst, and most likely. For this study, patterns of 100 drill holes were composed of 10 fences spaced 1000–5000 feet (305–1524 m) apart, each with 10 holes spaced 200–1000 feet (61–305 m) apart. In all, 25 grids were used with zero to three levels of follow-up drilling. The 600/2000 grid, with drill holes spaced 600 feet (183 m) apart in fences spaced 2000 feet (610 m) apart, was compared with the 200/5000 grid because they represented contrasting outcomes. The 600/2000 grid penetrated many ore bodies consistently but with few multiple hits to individual ore bodies; whereas the 200/5000 grid inconsistently penetrated few ore bodies with many multiple hits. The 600/2000 grid was more efficient than the 200/5000 grid at hitting large ore bodies of 1,000,000 short tons or greater (900,000 metric tons or greater) and was made more effective by adding one cycle of follow-up drilling. The 600/2000 grid had a 97% chance of hitting one or more large ore bodies with at least one drill hole per ore body, and the 200/5000 grid had a 64% chance. Once hit, there was an 82% chance that the largest ore body would be penetrated by three or more holes when using the 600/2000 grid and an 88% chance using the 200/5000 grid.